By Mellor J.W.
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Extra info for A Comprehensive Treatise Inorganic and Theoretical Chemistry
Here, 53,000 cals. of Flu. -Relation between the Yields energy are eq' to 53,000t0'24 of Chlorine Oxygen with Hydro=220,800 joules of eIectrica1 energy per gram ,hlOric Acid of Different Concentra eq. ; and since 96,540 coulombs will liberate a tiofis. gram-eq. 3 volts are needed to liberate a gram-eq. of sodium and chlorine, on the assumption that the electrical energy is eq. to the thermal value of the reaction. I n practice a greater voltage is needed; this is in part due to the expenditure of energy in overcoming the resistance of the electrolyte.
2Mn02. CaO +2CaO +2MnCI, +O, =2(Ca0,2Mn02)+CaCI,. The slurry is run into settlers, where the manganite deposits as a thin mud-Weldon mud. The clear liquid-largely calcium chloride-is run to waste ; no use has been found for but a very limited quantity of this by-product. The mud is pumped iuto special chlorino stills where it ismixed with hydrochloric acid. The mixture is warmed by blowing i n steam. After the chlorine has ceased t o be evolved, the residual liquid is treated as before. The circulation or transport of the iiquids and slimes is effected wholly by pumping machinery ; the time required for completing one cycle is comparatively short ; and the plant is simple and inexpensive.
1272, 1902. a P. Klason, Rer,, 23. 330, 1890. 4 F. Stolba, Rer. bdhm. Ces. , 11. , 211. 232, 1874 ; A. Michaelis, Lehrbz~chder anorganischen Chewtie, Braunschwsig, 1. 272, 1878 ; P. Mohr, Commentar zur 3weuss$chen Pharrnacopoe, Braunschweig, 98, 1858 ; H. Moissan and A. B. dc Jassonneix, Compt. , 137. 1108, 1903 ; W. Hampe, Chem. , 14. 1777, 1890 ; H. Ditz, Zed. angeoo. , 14. 6, 1901 ; F. P. Treadwell and W. A. K. , 18. 1931, 1905; L. Moser, Zeit. awrg. , 110. 125, 1920. J. A. Harker, Zeit,. phys.
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