By A.E. Shilov, Georgiy B. Shul'pin, Alexander E. Shilov
This monograph is dedicated to the activation and diverse modifications of saturated hydrocarbons (alkanes), i.e. reactions observed by way of the C--H and C--C bond cleavage. Alkanes are the most materials of oil and average gasoline, and for this reason are the primary feedstocks for the chemical undefined. nevertheless, those ingredients are recognized to be the least reactive natural compounds. specific realization is paid to the lately discovered alkane activations in the presence of steel complexes, that are defined in additional element. as well as the reactions of saturated hydrocarbons that are the major subject of this e-book, the activation of C--H bonds in arenes or even olefins and acetylenes are thought of. The monograph could be worthwhile not just should you have an interest in the activation of alkanes and different hydrocarbons by means of steel complexes, but in addition for experts in homogeneous and heterogeneous catalysis, petrochemistry, and organometallic chemistry. a few components of the monograph might be of curiosity for experts in inorganic and natural chemistry, theoretical chemistry, biochemistry or even biology, and additionally in the event you paintings within the petrochemical undefined, business natural synthesis and biotechnology.
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C) Doxsee, K. ; Grubbs, R. H. J. Am. Chem. Soc. 1981, 103, 7696. (d) Trautman, R. ; Gross, D. ; Ford, P. C. J. Am. Chem. Soc. 1985, 107, 2355. ; Dedieu, A. Theor. Chim. Acta 1982, 61, 587. ; Nakamura, S. Nouv. J. Chim. 1984, 8, 317. ; Green, M. L. H. J. Organomet. Chem. 1983, 250, 395. (b) Crabtree, R. ; Hamilton, D. G. Adv. Organomet. Chem. 1988, 28, 299. (c) Ginzburg, A. ; Bagatur’yants, A. A. Metalloorg. Khim. 1989, 2, 249 (in Russian). (d) Crabtree, R. H. Acc. Chem. Res. 1990, 23, 95. (e) Crabtree, R.
C. J. Am. Chem. Soc. 1985, 107, 2355. ; Dedieu, A. Theor. Chim. Acta 1982, 61, 587. ; Nakamura, S. Nouv. J. Chim. 1984, 8, 317. ; Green, M. L. H. J. Organomet. Chem. 1983, 250, 395. (b) Crabtree, R. ; Hamilton, D. G. Adv. Organomet. Chem. 1988, 28, 299. (c) Ginzburg, A. ; Bagatur’yants, A. A. Metalloorg. Khim. 1989, 2, 249 (in Russian). (d) Crabtree, R. H. Acc. Chem. Res. 1990, 23, 95. (e) Crabtree, R. H. Angew. , Int. Ed. Engl. 1993, 32, 789. (f) Heinekey, D. ; Oldham, W. , Jr. Chem. Rev. 1993, 93, 913.
15 %, ratio aldehyde/alcohol is 3 : 1) [37b]. Benzyl hydroperoxide is the initial product of this reaction which decomposes further to yield more stable oxygenates [37c]. Photosensitized oxidation of hydrocarbons by oxygen or air gives alkyl hydroperoxides, ketones and alcohols in much higher yields.
