Download Ciba Foundation Symposium 2 - Carbon-Fluorine Compounds; PDF

Content:
Chapter 1 advent (pages 1–7): Sir Rudolph Peters
Chapter 2 Chemical features of the Carbon?Fluorine Bond (pages 9–32): B. C. Saunders
Chapter three The actual houses of the Carbon?Fluorine Bond (pages 33–54): A. G. Sharpe
Chapter four a few Metabolic features of Fluoroacetate particularly concerning Fluorocitrate (pages 55–76): Sir Rudolph Peters
Chapter five influence of Fluoro Compounds on Metabolic keep an eye on in mind Mitochondria (pages 77–93): E. Martin Gal
Chapter 6 Fluorine as a Substituent for Oxygen in organic structures: Examples in Mammalian Membrane delivery and Glycosidase motion (pages 95–123): J. E. G. Barnett
Chapter 7 The Nucleotides of Fluorinated Pyrimidines and Their organic actions (pages 125–140): Charles Eidelberger
Chapter eight Fluoroamino Acids and Protein Synthesis (pages 141–167): L. Fowden
Chapter nine Synthesis and Reactivity of Fluorocarbohydrates (pages 169–213): P. W. Kent
Chapter 10 The Metabolism and Enzymology of Fluorocarbohydrates and similar Compounds (pages 214–238): N. F. Taylor
Chapter eleven Nuclear Magnetic Resonance experiences of Macromolecules with Fluorine Nuclei as Probes (pages 239–279): Raymond A. Dwek
Chapter 12 Chemistry of Fluorosteroids and Their Hormonal houses (pages 281–301): A. Wettstein
Chapter thirteen Biochemical results of Fluoroacetate Poisoning in Rat Liver (pages 303–333): P. Buffa, V. Guarriera?Bobyleva and that i. Pasquali?Ronchetti
Chapter 14 using Microorganisms within the learn of Fluorinated Compounds (pages 335–356): Peter Goldman
Chapter 15 medical and Pathological results of Fluoride Toxicity in Animals (pages 357–388): James L. Shupe
Chapter sixteen Chairman's Concluding feedback (page 189): Sir Rudolph Peters

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Extra info for Ciba Foundation Symposium 2 - Carbon-Fluorine Compounds; Chemistry, Biochemistry and Biological Activities

Example text

If so, what particular features of the structures and what properties are most important, and how can they be used to make at least qualitative predictions if quantitative treatment is impossible or too difficult? g. Gilliom 1969; Gould 1959; Gucker and Seifert 1967; Moore 1963). CHEMICAL EQUILIBRIA AND KINETICS Any physical or chemical change may be represented by means of a general equation 34 A . Sharpe aA + bB + ... + pP + qQ + ... (1) in which the physical states of all substances are specified.

A typical progression is given by CC1,F (1102 cm-'), CC12F2 (1155 and 1095 cm-'), and CClF3 (1210 and 1102 cm-') (Brown and Morgan 1965; Conley 1966). It is tempting to try to establish correlations between stretching frequencies, bond lengths, and bond energies, but it must be borne in mind (i) that molecules vibrate as a whole, and the idea of characteristic bond frequencies is always an approximation and sometimes an untenable one, and (ii) that even for a series of very closely related molecules a simple quantitative relationship between the stretching frequency and the bond energy is not necessarily to be expected.

L. E. and B. C. SAUNDERS (1960) Tetrahedron 10, 160. BRONNERT, D. L. E. and B. C. SAUNDERS (1965) Tetrahedron 21,3325. BROWN, P. J. and B. C. SAUNDERS (1962) Chem. & Znd. 307. BUCKLE, F. , R. HEAPand B. C. SAUNDERS (1949) J. Chem. 912. BUCKLE, F. , F. L. M. PATCISONand B. C. SAUNDERS (1949) J. Chem. 1471. CHAPMAN, N. , R. HEAPand B. C. SAUNDERS (1948) Analyst (Lond,) 73,434. GOLDMAN, P. (1972) This Volume, pp. 335-349. , A. SPORZYNSKI and J. WNUK (1947) Recl. Trav. Chim. Pays-Bas Be&. 66,419. HOFFMANN, F.

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