By D. L. Kepert, K. Vrieze
Compounds of the Transition components related to Metal-Metal Bonds offers with compounds of the transition components related to metal-metal bonds, with specific emphasis on metal-metal bonds in coordination compounds and organometallic complexes, halides, and oxides. components that effect the formation, balance, and houses of such compounds, in addition to their software in quite a few fields of chemistry and physics, are mentioned.
This publication is split into 4 sections and starts with a category of metal-metal bonds and a few of the actual and chemical equipment used to check them, together with X-ray crystallography, magnetic susceptibility and electron spin resonance, nuclear spin resonance, Mössbauer measurements, infrared and Raman spectroscopy, obvious and ultraviolet spectroscopy, mass spectrometry, electric conductivity, electrochemical tools, and chemical reactivity. elements influencing the power of metal-metal bonds in metals and compounds also are tested. the rest sections take care of metal-metal bonds in coordination compounds and organometallic complexes, halides, and oxides.
This monograph could be an invaluable source for inorganic chemists.
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Additional resources for Compounds of the Transition Elements Involving Metal–Metal Bonds
Sample text
CO Mn Mu oc c ο C O C Ο FIG. 25. Suggested structure for the Mn2(CO)gXi~ anion. If, however, halogen (CI2) is used, rupture of the metal-metal bond with the formation 1 of (CO) 5 MnCl takes p l a c e " . In the case of rhenium, reaction with halide ions and Re2(CO)io yielded metal2 metal bonded R e 2 ( C O ) 8 I T and the halogen bridged R e 2 ( C O ) 7 X 7 (X = CI, Br) and 17 2 R e 2 ( C O ) 7 C l 2 B r - » . The infrared spectrum of R e 2 ( C O ) 8 I T is, similar to that of Mn2(CO)8l|", as is probably its structure.
G. Johnson, R. D. Johnston, J. Lewis and B. H. Robinson, Chem. Communs. (1966) 851. 204 w . Fellman, D . K. Huggins and H. D . Kaesz, Proc. , p. 255. Ed. V. Gutmann, Vienna (1964). 240 TRANSITION METAL-METAL BONDS: D . L. KEPERT AND K. VRIEZE A reaction of Os3(CO)i2 with N a B H 4 afforded two complexes of which for one at least 203 five hydrogen atoms per Os 4(CO)i2 unit were f o u n d . Treatment of O s 0 4 in methanol with carbon monoxide at various temperatures and pressures yielded in addition to Os 3(CO)i2 the hydrides H O s 2 ( C O ) i 0 ( O H ) , HOs 3 (CO)i 0 (OMe), O s 3 ( C O ) i 0 ( O M e ) 2 , and 2 0 5 H20s 3(CO)io .
Mason and Α. I. M. Rae, / . Chem. Soc. (A) (1968) 778. " E. R. Corey and L. F. Dahl, Inorg. Chem. 1 (1962) 521. 1 G. Gardner-Summer, H. P. Klug and L. E. Alexander, Acta Cryst. 17 (1964) 732. m P. Corradini, / . Chem. Phys. 31 (1959) 1676, n C. H. Wei and L. F. Dahl, / . Am. Chem. Soc. 88 (1966) 1821. °p C. H. Wei, G. R. Wilkes and L. F. Dahl, / . Am. Chem. Soc. 89 (1967) 4792. E. R. Corey, L. F. Dahl and W. Beck, / . Am. Chem. Soc. 85 (1963) 1202. r A. F. , Clarendon Press, Oxford (1962). s L.
