By Jie Jack Li
In this 5th variation of Jack Jie Li's seminal "Name Reactions", the writer has extra twenty-seven new identify reactions to mirror the hot advances in natural chemistry. As in prior variants, every one response is delineated through its unique step by step, electron-pushing mechanism and supplemented with the unique and the newest references, particularly from assessment articles. Now with addition of many manmade purposes, this e-book isn't just an necessary source for complicated undergraduate and graduate scholars, yet can be a very good reference publication for all natural chemists in either and academia.
Unlike different books on identify reactions in natural chemistry, identify Reactions, a suite of specified response Mechanisms and artificial functions specializes in the response mechanisms. It covers over 320 classical in addition to modern identify reactions.
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Additional resources for Name Reactions: A Collection of Detailed Reaction Mechanisms
Example text
McKee, J. ; Zanger, M. ]. Chem. Educ. 1991, 68, A242. 13 Baeyer-Villiger oxidation General scheme: + The most electron-rich alkyl group (more substituted carbon) migrates first. : o if m-CPBA .. 0 o H+ ~ CI alkyl migration .. (y V O~ g ~O I ~ + HO References 1. 2. 3. 4. 5. 6. 7. v. ; Villiger, V. Ber. 1899, 32, 3625. Krow, G. R. Org. React. 1993, 43,251. ; Meunier, B. ]. Org. Chem. 1999, 4, 737. ; Beckmann, O. Compr. Asymmetric Catai. I-III1999, 2, 803. Crudden, C. ; Chen, A. ; Calhoun, L. A. Angew.
Chem. 1996, 74, 1321. Naicker, K. ; Varma, R. S. Catal. Lett. 1999, 58,167. 16 Bamford-Stevens reaction The Bamford-Stevens reaction and the Shapiro reaction share a similar mechanistic pathway. , whereas the latter employs a base such as alkyllithiums and Grignard reagents. As a result, the Bamford-Stevens reaction furnishes the moresubstituted ole fins as the thermodynamic products, while the Shapiro reaction generally affords the less-substituted olefins as the kinetic products. NaOMe - .. - In protic solvent: R:~N&_ - References 1.
Beusker, P. ; Aben, R. W. -P. ; Smits, J. M. ; Scheeren, H. W. ]. Org. Chem. 1998,2483. 42 Borsche-Drechsel cyclization Cl Fisher indole synthesis. 09 Hel ~ lJ-Nr .. H H 6~ ~ N/N H o~2 -- ~ H+ ~r; UN): I")N/NH [3,3]-sigmatropic rearrangement .. H ~J~+ crc~2 ~ lJ-, H References 1. 2. 3. ]. Prakt. Chem. 1858, 38,69. Atkinson, C. ; Biddle, B. N. ]. Chem. Soc. (C) 1966, 2053. ; Viel, C. C. R. Hebd. Seances Acad. , Ser. C 1977, 284, 377. 43 Boulton-Katritzky rearrangement Rearrangement of one five-membered heterocycle into another under thermolysis .
